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Freezing mixture temperature calculator

Find the temperature of an ice-salt mixture: a salt molality of 1.5 mol/kg in water, with a cryoscopic constant of 1.86, lowers the freezing point by 2.79 °C, to −2.79 °C. Works for other solvents too. Free in your browser.

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If you enter
Molality
1.5
Cryoscopic
1.86
You get
Kf
1.86
Pure freezing point
0
T0
0
Depression
2.79

Road crews, food technologists, and physical-chemistry students all need the same number: how far does dissolved salt pull the freezing temperature of an ice-water mixture below zero? Colligative freezing-point depression answers that with a short formula once molality and the solvent cryoscopic constant are known.

How dissolved salt pulls the freezing point down

Freezing-point depression is a colligative effect: it depends on how many solute particles are dissolved, not on what they are. For a dilute solution the drop is the cryoscopic constant of the solvent times the molality of the salt, and molality counts moles of solute per kilogram of solvent. For water and ice at standard pressure the pure freezing point is 0 °C and the constant is about 1.86 °C·kg/mol, so a molality of 1.5 mol/kg lowers the freezing point by 2.79 °C, to −2.79 °C. The calculator gives you both the size of the drop and the resulting temperature of the mixture.

Where it is used and what to watch

Road crews, food technologists, lab technicians preparing cold-room brines and chemistry students all need the same number. The most common mistake is to use molarity, which counts per litre of solution, instead of molality, which counts per kilogram of solvent and stays well defined when density changes with temperature. Another is to keep the constant for water when the solvent is different; in that case, enter the solvent's own constant and its pure freezing point. A molality of zero returns no depression, and a negative one is refused.

What freezing-point depression means and how to choose m and Kf

Write the classical dilute-solution law as delta T sub f equals cryoscopic constant K sub f times salt molality m. Molality is moles of solute per kilogram of solvent, not per liter of solution, so it stays well defined when density changes with temperature.

For pure water and ice at standard pressure the pure freezing point T sub zero is zero degrees Celsius and the tabulated cryoscopic constant is about one point eight six degrees Celsius kilogram per mole; other solvents use their own K sub f and T sub zero. Negative molality is invalid input because molality cannot be negative in a physical preparation; zero molality correctly returns no depression and T sub f equal to T sub zero.

Homework and exam verification

Students compute ΔTf = Kf × m for ice-water or other solvents, check the depressed freezing temperature against worked solutions, and get a clear error when negative molality is submitted by mistake.

Lab prep and brine estimates

Technicians turn measured or planned salt molality and a tabulated cryoscopic constant into the expected freezing temperature before cold-room or cryoscopy notebook entries.

What Kf should I use for water or ice?

Standard dilute-solution tables give Kf ≈ 1.86 °C·kg/mol for water.

Is the freezing mixture temperature calculator free?

The browser tool runs free on your device.

Does this multiply by the van't Hoff factor i?

No. It uses ΔTf = Kf × m only. For electrolytes, pass effective particle molality (i × formula molality) as molality, or compute i with a van't Hoff tool first.

Why does the calculation use molality instead of molarity?

Molality counts moles of salt per kilogram of solvent, so it does not change when the liquid expands or contracts with temperature. Molarity counts per litre of solution and drifts with density, which makes it a poor basis for freezing-point work.

Can I use it for a solvent other than water?

Yes. Enter that solvent's own cryoscopic constant and, if it does not freeze at 0 °C, its pure freezing point. The calculator then subtracts the depression from that temperature instead of from zero.

Everything on this page is available programmatically. This section is for teams who want to wire it into their own systems; everyone else can just use the tool above.

POSThttps://api.kit.forhosting.com/chem/freezing-mixture-temperature

Prefer to automate it? One authenticated POST creates the task; the result comes back by webhook or a signed link. The same capability also runs here on the web, by email and from Telegram — and soon from our app too.

curl -X POST https://api.kit.forhosting.com/chem/freezing-mixture-temperature \
  -H "Authorization: Bearer $KIT_KEY" \
  -H "Content-Type: application/json" \
  -d '{"molality":1.5,"cryoscopic_constant":1.86}'
{
  "molality": 1.5,
  "cryoscopic_constant": 1.86
}
{
  "task_id": "tsk_a1b2c3d4e5f6a1b2c3d4e5f6",
  "type": "chem.freezing_mixture_temperature",
  "status": "queued",
  "_links": {
    "result": "/tasks/tsk_…/result"
  }
}

The API is asynchronous: the call returns a task_id immediately and the result arrives by webhook. Polling is capped at 1 req/s per task.

Per request$0.002

Published price — no tokens, no invented credits. A failed task is never charged.

HTTPCodeMeaning
401unauthorizedMissing or invalid API key.
402insufficient_balanceYour balance doesn't cover the task price.
404unknown_typeThat task type doesn't exist.
429rate_limitedToo many requests. Use the webhook instead of polling.

This capability applies that law deterministically, returns both the depression magnitude and the absolute freezing temperature of the mixture, rejects negative molality with a clear invalid input error, and emits JSON that lab notebooks, homework checkers, and winter-ops pipelines can pin in tests without a full thermodynamics package.

What freezing-point depression means and how to choose m and Kf

Send the required field molality as a non-negative finite JSON number or numeric string in moles per kilogram; aliases m, molal, salt_molality, and b are accepted when documented. Send cryoscopic_constant as a finite number strictly greater than zero in degrees Celsius kilogram per mole; aliases Kf, kf, K_f, cryoscopic, and freezing_constant map to the same field. Optional pure_freezing_point defaults to zero for ice-water mixtures and can be set when the pure solvent freezes at another temperature. Identical inputs always produce identical JSON because the path is pure arithmetic with no network, no random seed, and no wall clock.

Reading depression, freezing temperature, and the response fields

On success the response echoes molality, cryoscopic_constant, and pure_freezing_point, duplicates the constant as Kf and the pure point as T0 for convenience, and reports depression together with delta_Tf as the product K sub f times m in degrees Celsius. The depressed mixture temperature appears as freezing_temperature and Tf, equal to T sub zero minus the depression. Unit labels unit_temperature, unit_molality, and unit_Kf document degrees Celsius, moles per kilogram, and degrees Celsius kilogram per mole so UIs can print axes without hard-coding. Formula is always delta T f equals K f times m semicolon T f equals T zero minus delta T f, and method is always freezing_point_depression so downstream code can branch without sniffing shapes. Use depression when a lab sheet only needs how many degrees the freezing point fell; use freezing_temperature when a brine chart or cold-storage setpoint needs the absolute temperature of the ice-salt mixture. Missing molality, missing cryoscopic constant, non-finite values, non-positive K sub f, and negative molality all fail with invalid_input and are not charged. If your solute is an electrolyte and you already work with particle molality equal to i times formula molality, send that effective molality here; this endpoint does not multiply by a separate van't Hoff factor.

API usage, pricing, lab and field workflows, and practical limits

Call the free in-browser freezing mixture temperature calculator for homework checks, lecture demos, road-salt planning sketches, and quick lab-prep verification without installing a thermodynamics package. The dilute-solution law is an approximation: very concentrated brines and eutectic regions need phase diagrams, not K sub f alone, so keep classroom and engineering estimates inside the dilute regime your tabulated constant assumes. Send a JSON body with the required non-negative molality and a positive cryoscopic constant, optionally overriding pure_freezing_point when the solvent is not water. Use the prepaid API when a tutoring platform, LIMS script, cold-chain planner, curriculum generator, or process pipeline needs a stable contract under KIT balance at $0.002 per successful item; validation failures never consume balance after the engine rejects the request. Pair this endpoint with a van't Hoff factor calculator when you first need i from ions and dissociation, then feed an effective molality equal to i times formula molality into this tool to estimate the ice-salt freezing temperature. Authors shipping SDKs can map freezing_temperature and depression directly into tables that show molality, K sub f, delta T f, and T f side by side—the same columns students write when they prepare freezing-point depression calculations by hand for ice-salt mixtures.

Tutoring and curriculum generators

Lesson builders produce structured JSON for drills on freezing-point depression without embedding a full physical-chemistry stack, and pin golden fixtures because the product is deterministic.

How do I calculate the freezing temperature of an ice-salt mixture?

Send JSON with molality (m in mol/kg, ≥ 0) and cryoscopic_constant (Kf > 0, e.g. 1.86 for water). The response includes depression ΔTf = Kf × m and freezing_temperature Tf = T0 − ΔTf (T0 defaults to 0 °C).

What happens if molality is negative?

The request fails with invalid_input. Molality cannot be negative; the capability rejects that case and does not charge the request.

Read the full KIT documentation →