Concentration cell potential calculator
Silver ions at 0.001 and 0.1 mol/L form a concentration cell whose voltage comes from that hundredfold difference, since the standard potential is zero. Enter both concentrations and the electrons to get the potential at 298.15 K or another temperature. Free in your browser.
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Worked example
- C anode
- 0.001
- C cathode
- 0.1
- N
- 1
- T
- 298.15
- Ratio
- 100
- Ln ratio
- 4.605170186
- Log10 ratio
- 2
A concentration cell is a galvanic cell in which both half-cells use the same redox couple but different ion activities, so the standard cell potential is zero and the entire voltage comes from the concentration gradient. Given the anode and cathode ion concentrations, the electrons transferred in the balanced half-reaction, and optionally absolute temperature, this concentration cell potential calculator applies the Nernst equation with E° equal to zero and returns the cell potential E in volts with a deterministic SI formula—no tables, no network, and no random drift. Students use it to check silver, copper, and zinc concentration-cell homework; lab software uses the same contract to pin expected millivolt values when both compartments share one metal ion. Zero concentration in either half-cell is rejected as invalid input because the logarithm of the concentration ratio is undefined.
Where the voltage of a concentration cell comes from
A concentration cell uses the same redox couple in both compartments, for example silver ions over silver metal, but at two different concentrations. Because the two half-cells are chemically identical, the standard potential is zero and the whole voltage comes from the concentration gradient. The calculator applies the Nernst equation with a standard potential of zero: it multiplies the gas constant by the temperature, divides by the number of electrons and the Faraday constant, and multiplies by the natural logarithm of the cathode concentration over the anode concentration.
Reading the result and avoiding common mistakes
At 25 °C, the default of 298.15 K, the voltage is about 0.05916 V divided by the number of electrons for every tenfold difference in concentration. A cell at 0.001 and 0.1 mol/L with one electron, like silver, has a hundredfold ratio and therefore gives twice that value; copper, with two electrons, would give half as much for the same ratio. Use the same unit for both concentrations so their ratio has no unit. A zero concentration is rejected because the logarithm would be undefined, and swapping the anode and cathode values flips the sign of the voltage.
FAQ
How do I calculate concentration cell potential?
Optional T is temperature in kelvin (default 298.15).
Why is E° zero for a concentration cell?
Both half-cells use the same redox couple; only the ion activities differ. The standard cell potential cancels, and the entire voltage comes from the concentration ratio in the Nernst term.
What temperature is used by default?
If you omit T, the calculator uses 298.15 K (25 °C). At that temperature the log10 slope is about 0.05916 V, matching common textbook forms.
Is the concentration cell potential calculator free?
The browser tool runs free on your device.
Which compartment is the anode in a concentration cell?
The dilute one. Oxidation happens in the compartment with the lower concentration and reduction in the more concentrated one, which gives a positive voltage. If you swap the two values, the result keeps the same size but turns negative.
Related tools
For developers — API access
Everything on this page is available programmatically. This section is for teams who want to wire it into their own systems; everyone else can just use the tool above.
API endpoint
Prefer to automate it? One authenticated POST creates the task; the result comes back by webhook or a signed link. The same capability also runs here on the web, by email and from Telegram — and soon from our app too.
Call it from your stack
curl -X POST https://api.kit.forhosting.com/chem/nernst-concentration-cell \
-H "Authorization: Bearer $KIT_KEY" \
-H "Content-Type: application/json" \
-d '{"c_anode":0.001,"c_cathode":0.1,"n":1}'const res = await fetch("https://api.kit.forhosting.com/chem/nernst-concentration-cell", {
method: "POST",
headers: {
"Authorization": `Bearer ${process.env.KIT_KEY}`,
"Content-Type": "application/json"
},
body: JSON.stringify({
"c_anode": 0.001,
"c_cathode": 0.1,
"n": 1
})
});
const { task_id } = await res.json();import os, requests
res = requests.post(
"https://api.kit.forhosting.com/chem/nernst-concentration-cell",
headers={"Authorization": f"Bearer {os.environ['KIT_KEY']}"},
json={
"c_anode": 0.001,
"c_cathode": 0.1,
"n": 1
},
)
task_id = res.json()["task_id"]<?php
$res = file_get_contents("https://api.kit.forhosting.com/chem/nernst-concentration-cell", false, stream_context_create([
"http" => [
"method" => "POST",
"header" => "Authorization: Bearer " . getenv("KIT_KEY") . "\r\nContent-Type: application/json",
"content" => '{"c_anode":0.001,"c_cathode":0.1,"n":1}',
],
]));
$task = json_decode($res, true);body := bytes.NewBufferString(`{"c_anode":0.001,"c_cathode":0.1,"n":1}`)
req, _ := http.NewRequest("POST", "https://api.kit.forhosting.com/chem/nernst-concentration-cell", body)
req.Header.Set("Authorization", "Bearer "+os.Getenv("KIT_KEY"))
req.Header.Set("Content-Type", "application/json")
res, _ := http.DefaultClient.Do(req)Example request
{
"c_anode": 0.001,
"c_cathode": 0.1,
"n": 1
}Example response
{
"task_id": "tsk_a1b2c3d4e5f6a1b2c3d4e5f6",
"type": "chem.nernst_concentration_cell",
"status": "queued",
"_links": {
"result": "/tasks/tsk_…/result"
}
}The API is asynchronous: the call returns a task_id immediately and the result arrives by webhook. Polling is capped at 1 req/s per task.
Pricing
Published price — no tokens, no invented credits. A failed task is never charged.
Errors
| HTTP | Code | Meaning |
|---|---|---|
401 | unauthorized | Missing or invalid API key. |
402 | insufficient_balance | Your balance doesn't cover the task price. |
404 | unknown_type | That task type doesn't exist. |
429 | rate_limited | Too many requests. Use the webhook instead of polling. |
Technical notes
What a concentration cell needs: two concentrations, n, and temperature
Write the cell so oxidation occurs in the dilute (or assigned anode) compartment and reduction in the concentrated (or assigned cathode) compartment of the same couple. You need three quantities. Third, n, the moles of electrons cancelled in the balanced half-reaction—for silver ion plus electron going to silver metal, n equals one; for copper two plus, n equals two. Optionally send absolute temperature T in kelvin; if you omit it the engine uses two hundred ninety-eight point one five kelvin, the usual laboratory standard. First, c_anode, the ion concentration in the oxidation half-cell, typically in moles per litre for dissolved species. Second, c_cathode, the ion concentration in the reduction half-cell in the same unit system so the ratio is dimensionless for the activity approximation used in introductory electrochemistry. Because E° is identically zero for a pure concentration cell, the formula collapses to E equals RT over nF times the natural log of c_cathode over c_anode, with gas constant R and Faraday constant F fixed in SI units so results match textbook checks of the form E approximately zero point zero five nine one six over n times log base ten of the concentration ratio at twenty-five degrees. Identical inputs always produce identical JSON because the path is pure arithmetic with no network, no random seed, and no wall clock. Field aliases accept c1, c2, electrons, and temperature so homework parsers and SDK demos can use familiar names without rewriting payloads.
Reading E, the concentration ratio, logs, and the classroom log10 form
E_log10_form recomputes with that rewrite and should match E within ordinary floating-point noise, giving a cross-check for tutorials. On success the response echoes c_anode, c_cathode, n, and T, then reports E and E_volts as the concentration cell potential in volts. The ratio field is c_cathode divided by c_anode so you can show students the driving force as a single number: when cathode is more concentrated the ratio exceeds one, the log is positive, and E is positive in the written direction; when the labels are swapped the ratio drops below one and E becomes negative, signalling that spontaneous current would reverse the assigned electrodes. ln_ratio and log10_ratio expose both logarithms for grading software that checks intermediate steps. nernst_factor is RT over nF alone, useful when you want the prefactor without multiplying by the log. slope_log10 is RT times ln of ten over F—the familiar zero point zero five nine-ish volts factor at room temperature—so a UI can display the classroom rewrite E equals slope over n times log ten of the ratio. E0 is always zero to document that this path never adds a non-zero standard potential. constants lists R and F with units so lab notebooks can cite the exact SI values used. formula and method label the path as nernst_concentration_cell for downstream branching without sniffing shapes. Missing required fields, non-finite numbers, non-positive concentrations, non-positive T, and zero electrons all fail with invalid_input and are not charged after the engine rejects the request.
API usage, pricing, lab workflows, and practical limits
Call the free in-browser concentration cell potential calculator for homework checks, lecture demos, and quick intuition about how large a voltage a tenfold or hundredfold concentration gap can produce without installing a spreadsheet or a computer algebra system. Send a JSON body with required numeric fields c_anode, c_cathode, and n, plus optional T in kelvin when the experiment is not at twenty-five degrees Celsius. Use the prepaid API when a tutoring platform, electrochemistry lab notebook, corrosion-cell model, or curriculum generator needs a stable contract under KIT balance at $0.002 per successful item; validation failures never consume balance after rejection. Pair this endpoint with the general Nernst equation tool when you also need a non-zero E° and a full reaction quotient, or with equilibrium-constant tools when concentrations come from measured equilibria rather than stock solutions. Keep n non-zero and both concentrations strictly positive; extreme ratios still return finite E when the log is defined, but scientific notation in JSON remains the caller’s responsibility for display. Authors shipping SDKs can map E, ratio, and slope_log10 directly into UI rows that mirror the worked examples students write on paper when they apply the concentration-cell Nernst form by hand.
Integration use cases
Homework and exam verification
Students enter anode and cathode ion concentrations plus n for silver or copper concentration cells, compare E to worked solutions, and get a clear invalid_input error when either concentration is zero by mistake.
Lab notebooks and corrosion models
Electrochemistry labs and lightweight differential-aeration or metal-ion gradient models call a stable prepaid endpoint for millivolt predictions from measured compartment concentrations without reimplementing R, F, and ln in every language.
Tutoring platforms and curriculum generators
Lesson builders produce concentration-cell drills with structured JSON for flashcards and auto-graded quizzes, using the free browser widget for demos and the API for server-side grading at $0.002 per successful item.
Technical questions
What happens if a concentration is zero?
The request fails with invalid_input. Zero concentration makes ln(c_cathode/c_anode) undefined, so the engine rejects the input and does not charge.